blackoilsolventmodules.hh

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// -*- mode: C++; tab-width: 4; indent-tabs-mode: nil; c-basic-offset: 4 -*-
// vi: set et ts=4 sw=4 sts=4:
/*
  This file is part of the Open Porous Media project (OPM).
 
  OPM is free software: you can redistribute it and/or modify
  it under the terms of the GNU General Public License as published by
  the Free Software Foundation, either version 2 of the License, or
  (at your option) any later version.
 
  OPM is distributed in the hope that it will be useful,
  but WITHOUT ANY WARRANTY; without even the implied warranty of
  MERCHANTABILITY or FITNESS FOR A PARTICULAR PURPOSE.  See the
  GNU General Public License for more details.
 
  You should have received a copy of the GNU General Public License
  along with OPM.  If not, see <http://www.gnu.org/licenses/>.
 
  Consult the COPYING file in the top-level source directory of this
  module for the precise wording of the license and the list of
  copyright holders.
*/
#ifndef EWOMS_BLACK_OIL_SOLVENT_MODULE_HH
#define EWOMS_BLACK_OIL_SOLVENT_MODULE_HH
 
#include <dune/common/fvector.hh>
 
#include <opm/common/Exceptions.hpp>
 
#include <opm/material/common/MathToolbox.hpp>
#include <opm/material/common/Valgrind.hpp>
#include <opm/material/fluidsystems/blackoilpvt/SolventPvt.hpp>
 
#include <opm/models/blackoil/blackoilproperties.hh>
#include <opm/models/blackoil/blackoilsolventparams.hpp>
 
#include <opm/models/common/multiphasebaseparameters.hh>
#include <opm/models/common/quantitycallbacks.hh>
 
#include <opm/models/discretization/common/linearizationtype.hh>
 
#include <opm/models/io/vtkblackoilsolventmodule.hpp>
 
#include <algorithm>
#include <array>
#include <cassert>
#include <cmath>
#include <istream>
#include <memory>
#include <ostream>
#include <stdexcept>
#include <string>
 
namespace Opm {
 
template <class TypeTag, bool enableSolventV = getPropValue<TypeTag, Properties::EnableSolvent>()>
class BlackOilSolventModule
{
    using Scalar = GetPropType<TypeTag, Properties::Scalar>;
    using Evaluation = GetPropType<TypeTag, Properties::Evaluation>;
    using PrimaryVariables = GetPropType<TypeTag, Properties::PrimaryVariables>;
    using IntensiveQuantities = GetPropType<TypeTag, Properties::IntensiveQuantities>;
    using ExtensiveQuantities = GetPropType<TypeTag, Properties::ExtensiveQuantities>;
    using ElementContext = GetPropType<TypeTag, Properties::ElementContext>;
    using FluidSystem = GetPropType<TypeTag, Properties::FluidSystem>;
    using Model = GetPropType<TypeTag, Properties::Model>;
    using Simulator = GetPropType<TypeTag, Properties::Simulator>;
    using EqVector = GetPropType<TypeTag, Properties::EqVector>;
    using RateVector = GetPropType<TypeTag, Properties::RateVector>;
    using Indices = GetPropType<TypeTag, Properties::Indices>;
    using Toolbox = MathToolbox<Evaluation>;
    using SolventPvt = typename BlackOilSolventParams<Scalar>::SolventPvt;
    using Co2GasPvt = typename BlackOilSolventParams<Scalar>::Co2GasPvt;
    using H2GasPvt = typename BlackOilSolventParams<Scalar>::H2GasPvt;
    using BrineCo2Pvt = typename BlackOilSolventParams<Scalar>::BrineCo2Pvt;
    using BrineH2Pvt = typename BlackOilSolventParams<Scalar>::BrineH2Pvt;
 
    using TabulatedFunction = typename BlackOilSolventParams<Scalar>::TabulatedFunction;
 
    static constexpr unsigned solventSaturationIdx = Indices::solventSaturationIdx;
    static constexpr unsigned contiSolventEqIdx = Indices::contiSolventEqIdx;
    static constexpr unsigned enableSolvent = enableSolventV;
    static constexpr unsigned numEq = getPropValue<TypeTag, Properties::NumEq>();
    static constexpr unsigned numPhases = FluidSystem::numPhases;
    static constexpr bool blackoilConserveSurfaceVolume =
        getPropValue<TypeTag, Properties::BlackoilConserveSurfaceVolume>();
    static constexpr int waterPhaseIdx = FluidSystem::waterPhaseIdx;
 
public:
    static void setParams(BlackOilSolventParams<Scalar>&& params)
    { params_ = params; }
 
    static void setSolventPvt(const SolventPvt& value)
    { params_.solventPvt_ = value; }
 
    static void setIsMiscible(const bool isMiscible)
    { params_.isMiscible_ = isMiscible; }
 
    static void registerParameters()
    {
        if constexpr (enableSolvent) {
            VtkBlackOilSolventModule<TypeTag>::registerParameters();
        }
    }
 
    static void registerOutputModules(Model& model,
                                      Simulator& simulator)
    {
        if constexpr (enableSolvent) {
            model.addOutputModule(std::make_unique<VtkBlackOilSolventModule<TypeTag>>(simulator));
        }
    }
 
    static bool primaryVarApplies(unsigned pvIdx)
    {
        if constexpr (enableSolvent) {
            return pvIdx == solventSaturationIdx;
        }
        else {
            return false;
        }
    }
 
    static std::string primaryVarName([[maybe_unused]] unsigned pvIdx)
    {
        assert(primaryVarApplies(pvIdx));
 
        return "saturation_solvent";
    }
 
    static Scalar primaryVarWeight([[maybe_unused]] unsigned pvIdx)
    {
        assert(primaryVarApplies(pvIdx));
 
        // TODO: it may be beneficial to chose this differently.
        return static_cast<Scalar>(1.0);
    }
 
    static bool eqApplies(unsigned eqIdx)
    {
        if constexpr (enableSolvent) {
            return eqIdx == contiSolventEqIdx;
        }
        else {
            return false;
        }
    }
 
    static std::string eqName([[maybe_unused]] unsigned eqIdx)
    {
        assert(eqApplies(eqIdx));
 
        return "conti^solvent";
    }
 
    static Scalar eqWeight([[maybe_unused]] unsigned eqIdx)
    {
        assert(eqApplies(eqIdx));
 
        // TODO: it may be beneficial to chose this differently.
        return static_cast<Scalar>(1.0);
    }
 
    template <class LhsEval>
    static void addStorage(Dune::FieldVector<LhsEval, numEq>& storage,
                           const IntensiveQuantities& intQuants)
    {
        if constexpr (enableSolvent) {
            if constexpr (blackoilConserveSurfaceVolume) {
                storage[contiSolventEqIdx] +=
                        Toolbox::template decay<LhsEval>(intQuants.porosity()) *
                        Toolbox::template decay<LhsEval>(intQuants.solventSaturation()) *
                        Toolbox::template decay<LhsEval>(intQuants.solventInverseFormationVolumeFactor());
                if (isSolubleInWater()) {
                    storage[contiSolventEqIdx] +=
                        Toolbox::template decay<LhsEval>(intQuants.porosity()) *
                        Toolbox::template decay<LhsEval>(intQuants.fluidState().saturation(waterPhaseIdx)) *
                        Toolbox::template decay<LhsEval>(intQuants.fluidState().invB(waterPhaseIdx)) *
                        Toolbox::template decay<LhsEval>(intQuants.rsSolw());
                }
            }
            else {
                storage[contiSolventEqIdx] +=
                        Toolbox::template decay<LhsEval>(intQuants.porosity()) *
                        Toolbox::template decay<LhsEval>(intQuants.solventSaturation()) *
                        Toolbox::template decay<LhsEval>(intQuants.solventDensity());
                if (isSolubleInWater()) {
                    storage[contiSolventEqIdx] +=
                        Toolbox::template decay<LhsEval>(intQuants.porosity()) *
                        Toolbox::template decay<LhsEval>(intQuants.fluidState().saturation(waterPhaseIdx)) *
                        Toolbox::template decay<LhsEval>(intQuants.fluidState().density(waterPhaseIdx)) *
                        Toolbox::template decay<LhsEval>(intQuants.rsSolw());
                }
            }
        }
    }
 
    static void computeFlux([[maybe_unused]] RateVector& flux,
                            [[maybe_unused]] const ElementContext& elemCtx,
                            [[maybe_unused]] unsigned scvfIdx,
                            [[maybe_unused]] unsigned timeIdx)
 
    {
        if constexpr (enableSolvent) {
            const auto& extQuants = elemCtx.extensiveQuantities(scvfIdx, timeIdx);
 
            const unsigned upIdx = extQuants.solventUpstreamIndex();
            const unsigned inIdx = extQuants.interiorIndex();
            const auto& up = elemCtx.intensiveQuantities(upIdx, timeIdx);
 
            if constexpr (blackoilConserveSurfaceVolume) {
                if (upIdx == inIdx)  {
                    flux[contiSolventEqIdx] = extQuants.solventVolumeFlux() *
                                              up.solventInverseFormationVolumeFactor();
                }
                else {
                    flux[contiSolventEqIdx] = extQuants.solventVolumeFlux() *
                                              decay<Scalar>(up.solventInverseFormationVolumeFactor());
                }
 
 
                if (isSolubleInWater()) {
                    if (upIdx == inIdx) {
                        flux[contiSolventEqIdx] +=
                                extQuants.volumeFlux(waterPhaseIdx) *
                                up.fluidState().invB(waterPhaseIdx) *
                                up.rsSolw();
                    }
                    else {
                        flux[contiSolventEqIdx] +=
                                extQuants.volumeFlux(waterPhaseIdx) *
                                decay<Scalar>(up.fluidState().invB(waterPhaseIdx)) *
                                decay<Scalar>(up.rsSolw());
                    }
                }
            }
            else {
                if (upIdx == inIdx) {
                    flux[contiSolventEqIdx] = extQuants.solventVolumeFlux() * up.solventDensity();
                }
                else {
                    flux[contiSolventEqIdx] = extQuants.solventVolumeFlux() * decay<Scalar>(up.solventDensity());
                }
 
                if (isSolubleInWater()) {
                    if (upIdx == inIdx) {
                        flux[contiSolventEqIdx] +=
                                extQuants.volumeFlux(waterPhaseIdx) *
                                up.fluidState().density(waterPhaseIdx) *
                                up.rsSolw();
                    }
                    else {
                        flux[contiSolventEqIdx] +=
                                extQuants.volumeFlux(waterPhaseIdx) *
                                decay<Scalar>(up.fluidState().density(waterPhaseIdx)) *
                                decay<Scalar>(up.rsSolw());
                    }
                }
            }
        }
    }
 
    static void assignPrimaryVars(PrimaryVariables& priVars,
                                  Scalar solventSaturation,
                                  Scalar solventRsw)
    {
        if constexpr (!enableSolvent) {
            priVars.setPrimaryVarsMeaningSolvent(PrimaryVariables::SolventMeaning::Disabled);
            return;
        }
        // Determine the meaning of the solvent primary variables
        if (solventSaturation > 0 || !isSolubleInWater()) {
            priVars.setPrimaryVarsMeaningSolvent(PrimaryVariables::SolventMeaning::Ss);
            priVars[solventSaturationIdx] = solventSaturation;
        } else {
            priVars.setPrimaryVarsMeaningSolvent(PrimaryVariables::SolventMeaning::Rsolw);
            priVars[solventSaturationIdx] = solventRsw;
        } 
    }
 
    static void updatePrimaryVars(PrimaryVariables& newPv,
                                  const PrimaryVariables& oldPv,
                                  const EqVector& delta)
    {
        if constexpr (enableSolvent) {
            // do a plain unchopped Newton update
            newPv[solventSaturationIdx] = oldPv[solventSaturationIdx] - delta[solventSaturationIdx];
        }
    }
 
    static Scalar computeUpdateError(const PrimaryVariables&,
                                     const EqVector&)
    {
        // do not consider consider the cange of solvent primary variables for
        // convergence
        // TODO: maybe this should be changed
        return static_cast<Scalar>(0.0);
    }
 
    static Scalar computeResidualError(const EqVector& resid)
    {
        // do not weight the residual of solvents when it comes to convergence
        return std::abs(Toolbox::scalarValue(resid[contiSolventEqIdx]));
    }
 
    template <class DofEntity>
    static void serializeEntity(const Model& model, std::ostream& outstream, const DofEntity& dof)
    {
        if constexpr (enableSolvent) {
            const unsigned dofIdx = model.dofMapper().index(dof);
 
            const PrimaryVariables& priVars = model.solution(/*timeIdx=*/0)[dofIdx];
            outstream << priVars[solventSaturationIdx];
        }
    }
 
    template <class DofEntity>
    static void deserializeEntity(Model& model, std::istream& instream, const DofEntity& dof)
    {
        if constexpr (enableSolvent) {
            const unsigned dofIdx = model.dofMapper().index(dof);
 
            PrimaryVariables& priVars0 = model.solution(/*timeIdx=*/0)[dofIdx];
            PrimaryVariables& priVars1 = model.solution(/*timeIdx=*/1)[dofIdx];
 
            instream >> priVars0[solventSaturationIdx];
 
            // set the primary variables for the beginning of the current time step.
            priVars1 = priVars0[solventSaturationIdx];
        }
    }
 
    static const SolventPvt& solventPvt()
    { return params_.solventPvt_; }
 
    static const Co2GasPvt& co2GasPvt()
    { return params_.co2GasPvt_; }
 
    static const H2GasPvt& h2GasPvt()
    { return params_.h2GasPvt_; }
 
    static const BrineCo2Pvt& brineCo2Pvt()
    { return params_.brineCo2Pvt_; }
 
    static const BrineH2Pvt& brineH2Pvt()
    { return params_.brineH2Pvt_; }
 
    template <class ElemContext>
    static const TabulatedFunction& ssfnKrg(const ElemContext& elemCtx,
                                            unsigned scvIdx,
                                            unsigned timeIdx)
    {
        const unsigned satnumRegionIdx =
            elemCtx.problem().satnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.ssfnKrg_[satnumRegionIdx];
    }
 
    template <class ElemContext>
    static const TabulatedFunction& ssfnKrs(const ElemContext& elemCtx,
                                            unsigned scvIdx,
                                            unsigned timeIdx)
    {
        const unsigned satnumRegionIdx =
            elemCtx.problem().satnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.ssfnKrs_[satnumRegionIdx];
    }
 
    template <class ElemContext>
    static const TabulatedFunction& sof2Krn(const ElemContext& elemCtx,
                                            unsigned scvIdx,
                                            unsigned timeIdx)
    {
        const unsigned satnumRegionIdx =
            elemCtx.problem().satnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.sof2Krn_[satnumRegionIdx];
    }
 
    template <class ElemContext>
    static const TabulatedFunction& misc(const ElemContext& elemCtx,
                                         unsigned scvIdx,
                                         unsigned timeIdx)
    {
        const unsigned miscnumRegionIdx =
            elemCtx.problem().miscnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.misc_[miscnumRegionIdx];
    }
 
    template <class ElemContext>
    static const TabulatedFunction& pmisc(const ElemContext& elemCtx,
                                          unsigned scvIdx,
                                          unsigned timeIdx)
    {
        const unsigned miscnumRegionIdx =
            elemCtx.problem().miscnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.pmisc_[miscnumRegionIdx];
    }
 
    template <class ElemContext>
    static const TabulatedFunction& msfnKrsg(const ElemContext& elemCtx,
                                             unsigned scvIdx,
                                             unsigned timeIdx)
    {
        const unsigned satnumRegionIdx =
            elemCtx.problem().satnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.msfnKrsg_[satnumRegionIdx];
    }
 
    template <class ElemContext>
    static const TabulatedFunction& msfnKro(const ElemContext& elemCtx,
                                            unsigned scvIdx,
                                            unsigned timeIdx)
    {
        const unsigned satnumRegionIdx =
            elemCtx.problem().satnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.msfnKro_[satnumRegionIdx];
    }
 
    template <class ElemContext>
    static const TabulatedFunction& sorwmis(const ElemContext& elemCtx,
                                            unsigned scvIdx,
                                            unsigned timeIdx)
    {
        const unsigned miscnumRegionIdx =
            elemCtx.problem().miscnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.sorwmis_[miscnumRegionIdx];
    }
 
    template <class ElemContext>
    static const TabulatedFunction& sgcwmis(const ElemContext& elemCtx,
                                            unsigned scvIdx,
                                            unsigned timeIdx)
    {
        const unsigned miscnumRegionIdx =
            elemCtx.problem().miscnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.sgcwmis_[miscnumRegionIdx];
    }
 
    template <class ElemContext>
    static const TabulatedFunction& tlPMixTable(const ElemContext& elemCtx,
                                            unsigned scvIdx,
                                            unsigned timeIdx)
    {
        const unsigned miscnumRegionIdx =
            elemCtx.problem().miscnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.tlPMixTable_[miscnumRegionIdx];
    }
 
    template <class ElemContext>
    static Scalar tlMixParamViscosity(const ElemContext& elemCtx,
                                      unsigned scvIdx,
                                      unsigned timeIdx)
    {
        const unsigned miscnumRegionIdx =
            elemCtx.problem().miscnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.tlMixParamViscosity_[miscnumRegionIdx];
    }
 
 
    template <class ElemContext>
    static Scalar tlMixParamDensity(const ElemContext& elemCtx,
                                    unsigned scvIdx,
                                    unsigned timeIdx)
    {
        const unsigned miscnumRegionIdx =
            elemCtx.problem().miscnumRegionIndex(elemCtx, scvIdx, timeIdx);
        return params_.tlMixParamDensity_[miscnumRegionIdx];
    }
 
    static bool isMiscible()
    { return params_.isMiscible_; }
 
    template <class Value>
    static Value solubilityLimit(unsigned pvtIdx, const Value& temperature,
                                 const Value& pressure, const Value& saltConcentration)
    {
        if (!isSolubleInWater()) {
            return 0.0;
        }
 
        assert(isCO2Sol() || isH2Sol());
        if (isCO2Sol()) {
            return brineCo2Pvt().saturatedGasDissolutionFactor(pvtIdx, temperature,
                                                               pressure, saltConcentration);
        }
        else {
            return brineH2Pvt().saturatedGasDissolutionFactor(pvtIdx, temperature,
                                                              pressure, saltConcentration);
        }
    }
 
    static bool isSolubleInWater() 
    { return params_.rsSolw_active_; }
 
    static bool isCO2Sol() 
    { return params_.co2sol_; }
 
    static bool isH2Sol() 
    { return params_.h2sol_; }
 
private:
    static BlackOilSolventParams<Scalar> params_; // the krg(Fs) column of the SSFN table
};
 
template <class TypeTag, bool enableSolventV>
BlackOilSolventParams<typename BlackOilSolventModule<TypeTag, enableSolventV>::Scalar>
BlackOilSolventModule<TypeTag, enableSolventV>::params_;
 
template <class TypeTag, bool enableSolventV>
class BlackOilSolventIntensiveQuantities;
 
template <class TypeTag>
class BlackOilSolventIntensiveQuantities<TypeTag, /*enableSolventV=*/true>
{
    using Implementation = GetPropType<TypeTag, Properties::IntensiveQuantities>;
 
    using Scalar = GetPropType<TypeTag, Properties::Scalar>;
    using Evaluation = GetPropType<TypeTag, Properties::Evaluation>;
    using PrimaryVariables = GetPropType<TypeTag, Properties::PrimaryVariables>;
    using FluidSystem = GetPropType<TypeTag, Properties::FluidSystem>;
    using MaterialLaw = GetPropType<TypeTag, Properties::MaterialLaw>;
    using Indices = GetPropType<TypeTag, Properties::Indices>;
    using Problem = GetPropType<TypeTag, Properties::Problem>;
    using ElementContext = GetPropType<TypeTag, Properties::ElementContext>;
 
    using SolventModule = BlackOilSolventModule<TypeTag>;
 
    enum { numPhases = getPropValue<TypeTag, Properties::NumPhases>() };
    static constexpr int solventSaturationIdx = Indices::solventSaturationIdx;
    static constexpr int oilPhaseIdx = FluidSystem::oilPhaseIdx;
    static constexpr int gasPhaseIdx = FluidSystem::gasPhaseIdx;
    static constexpr int waterPhaseIdx = FluidSystem::waterPhaseIdx;
    static constexpr double cutOff = 1e-12;
 
public:
    void solventPreSatFuncUpdate_(const ElementContext& elemCtx,
                                  unsigned dofIdx,
                                  unsigned timeIdx)
    {
        const PrimaryVariables& priVars = elemCtx.primaryVars(dofIdx, timeIdx);
        this->solventPreSatFuncUpdate_(priVars, timeIdx, elemCtx.linearizationType());
    }
 
    void solventPreSatFuncUpdate_(const PrimaryVariables& priVars,
                                  const unsigned timeIdx,
                                  const LinearizationType linearizationType)
    {
        auto& fs = asImp_().fluidState_;
        solventSaturation_ = 0.0;
        if (priVars.primaryVarsMeaningSolvent() == PrimaryVariables::SolventMeaning::Ss) {
            solventSaturation_ = priVars.makeEvaluation(solventSaturationIdx, timeIdx, linearizationType);
        }
 
        hydrocarbonSaturation_ = fs.saturation(gasPhaseIdx);
 
        // apply a cut-off. Don't waste calculations if no solvent
        if (solventSaturation().value() < cutOff) {
            return;
        }
 
        // make the saturation of the gas phase which is used by the saturation functions
        // the sum of the solvent "saturation" and the saturation the hydrocarbon gas.
        fs.setSaturation(gasPhaseIdx, hydrocarbonSaturation_ + solventSaturation_);
    }
 
    void solventPostSatFuncUpdate_(const ElementContext& elemCtx,
                                   unsigned dofIdx,
                                   unsigned timeIdx)
    {
        const PrimaryVariables& priVars = elemCtx.primaryVars(dofIdx, timeIdx);
        this->solventPostSatFuncUpdate_(elemCtx.problem(), priVars, elemCtx.globalSpaceIndex(dofIdx, timeIdx), timeIdx, elemCtx.linearizationType());
    }
 
private:
    // This class is a private implementation detail.
    template <class Problem>
    struct ProblemAndCellIndexOnlyContext
    {
        const Problem& problem_;
        unsigned int index_;
        const Problem& problem() const { return problem_; }
        unsigned int globalSpaceIndex([[maybe_unused]] const unsigned int spaceIdx,
                                      [[maybe_unused]] const unsigned int timeIdx) const
        {
            return index_;
        }
    };
 
public:
    void solventPostSatFuncUpdate_(const Problem& problem,
                                   const PrimaryVariables& priVars,
                                   const unsigned globalSpaceIdx,
                                   const unsigned timeIdx,
                                   const LinearizationType linearizationType)
    {
        // revert the gas "saturation" of the fluid state back to the saturation of the
        // hydrocarbon gas.
        auto& fs = asImp_().fluidState_;
        fs.setSaturation(gasPhaseIdx, hydrocarbonSaturation_);
 
        // update rsSolw. This needs to be done after the pressure is defined in the fluid state.
        rsSolw_ = 0.0;
        if (priVars.primaryVarsMeaningSolvent() == PrimaryVariables::SolventMeaning::Ss) {
            rsSolw_ = SolventModule::solubilityLimit(asImp_().pvtRegionIndex(),
                                                     fs.temperature(waterPhaseIdx),
                                                     fs.pressure(waterPhaseIdx),
                                                     fs.saltConcentration());
        } else if (priVars.primaryVarsMeaningSolvent() == PrimaryVariables::SolventMeaning::Rsolw) {
            rsSolw_ = priVars.makeEvaluation(solventSaturationIdx, timeIdx, linearizationType);
        }
 
        solventMobility_ = 0.0;
 
        // apply a cut-off. Don't waste calculations if no solvent
        if (solventSaturation().value() < cutOff) {
            return;
        }
 
        ProblemAndCellIndexOnlyContext<Problem> elemCtx{problem, globalSpaceIdx};
        unsigned dofIdx = 0; // Dummy
 
        // Pressure effects on capillary pressure miscibility
        if (SolventModule::isMiscible()) {
            const Evaluation& p =
                FluidSystem::phaseIsActive(oilPhaseIdx)
                    ? fs.pressure(oilPhaseIdx)
                    : fs.pressure(gasPhaseIdx);
            const Evaluation pmisc =
                SolventModule::pmisc(elemCtx, dofIdx, timeIdx).eval(p, /*extrapolate=*/true);
            const Evaluation& pgImisc = fs.pressure(gasPhaseIdx);
 
            // compute capillary pressure for miscible fluid
            Evaluation pgMisc = 0.0;
            std::array<Evaluation, numPhases> pC;
            const auto& materialParams = problem.materialLawParams(elemCtx, dofIdx, timeIdx);
            MaterialLaw::capillaryPressures(pC, materialParams, fs);
 
            // oil is the reference phase for pressure
            if (priVars.primaryVarsMeaningPressure() == PrimaryVariables::PressureMeaning::Pg) {
                pgMisc = priVars.makeEvaluation(Indices::pressureSwitchIdx, timeIdx,
                                                linearizationType);
            }
            else {
                const Evaluation& po =
                    priVars.makeEvaluation(Indices::pressureSwitchIdx,
                                           timeIdx, linearizationType);
                pgMisc = po + (pC[gasPhaseIdx] - pC[oilPhaseIdx]);
            }
 
           fs.setPressure(gasPhaseIdx, pmisc * pgMisc + (1.0 - pmisc) * pgImisc);
        }
 
        const Evaluation gasSolventSat = hydrocarbonSaturation_ + solventSaturation_;
 
        if (gasSolventSat.value() < cutOff) { // avoid division by zero
            return;
        }
 
        const Evaluation Fhydgas = hydrocarbonSaturation_ / gasSolventSat;
        const Evaluation Fsolgas = solventSaturation_ / gasSolventSat;
 
        // account for miscibility of oil and solvent
        if (SolventModule::isMiscible() && FluidSystem::phaseIsActive(oilPhaseIdx)) {
            const auto& misc = SolventModule::misc(elemCtx, dofIdx, timeIdx);
            const auto& pmisc = SolventModule::pmisc(elemCtx, dofIdx, timeIdx);
            const Evaluation& p =
                FluidSystem::phaseIsActive(oilPhaseIdx)
                    ? fs.pressure(oilPhaseIdx)
                    : fs.pressure(gasPhaseIdx);
            const Evaluation miscibility =
                misc.eval(Fsolgas, /*extrapolate=*/true) *
                pmisc.eval(p, /*extrapolate=*/true);
 
            // TODO adjust endpoints of sn and ssg
            const unsigned cellIdx = elemCtx.globalSpaceIndex(dofIdx, timeIdx);
            const auto& materialLawManager = elemCtx.problem().materialLawManager();
            const auto& scaledDrainageInfo =
                    materialLawManager->oilWaterScaledEpsInfoDrainage(cellIdx);
 
            const Scalar sogcr = scaledDrainageInfo.Sogcr;
            Evaluation sor = sogcr;
            if (FluidSystem::phaseIsActive(waterPhaseIdx)) {
                const Evaluation& sw = fs.saturation(waterPhaseIdx);
                const auto& sorwmis = SolventModule::sorwmis(elemCtx, dofIdx, timeIdx);
                sor = miscibility *
                      sorwmis.eval(sw,  /*extrapolate=*/true) + (1.0 - miscibility) * sogcr;
            }
            const Scalar sgcr = scaledDrainageInfo.Sgcr;
            Evaluation sgc = sgcr;
            if (FluidSystem::phaseIsActive(waterPhaseIdx)) {
                const Evaluation& sw = fs.saturation(waterPhaseIdx);
                const auto& sgcwmis = SolventModule::sgcwmis(elemCtx, dofIdx, timeIdx);
                sgc = miscibility * sgcwmis.eval(sw,  /*extrapolate=*/true) + (1.0 - miscibility) * sgcr;
            }
 
            Evaluation oilGasSolventSat = gasSolventSat;
            if (FluidSystem::phaseIsActive(oilPhaseIdx)) {
                oilGasSolventSat += fs.saturation(oilPhaseIdx);
            }
            const Evaluation zero = 0.0;
            const Evaluation oilGasSolventEffSat = std::max(oilGasSolventSat - sor - sgc, zero);
 
            Evaluation F_totalGas = 0.0;
            if (oilGasSolventEffSat.value() > cutOff) {
                const Evaluation gasSolventEffSat = std::max(gasSolventSat - sgc, zero);
                F_totalGas = gasSolventEffSat / oilGasSolventEffSat;
            }
            const auto& msfnKro = SolventModule::msfnKro(elemCtx, dofIdx, timeIdx);
            const auto& msfnKrsg = SolventModule::msfnKrsg(elemCtx, dofIdx, timeIdx);
            const auto& sof2Krn = SolventModule::sof2Krn(elemCtx, dofIdx, timeIdx);
 
            const Evaluation mkrgt = msfnKrsg.eval(F_totalGas, /*extrapolate=*/true) *
                                     sof2Krn.eval(oilGasSolventSat, /*extrapolate=*/true);
            const Evaluation mkro = msfnKro.eval(F_totalGas, /*extrapolate=*/true) *
                                    sof2Krn.eval(oilGasSolventSat, /*extrapolate=*/true);
 
            Evaluation& kro = asImp_().mobility_[oilPhaseIdx];
            Evaluation& krg = asImp_().mobility_[gasPhaseIdx];
 
            // combine immiscible and miscible part of the relperm
            krg *= 1.0 - miscibility;
            krg += miscibility * mkrgt;
            kro *= 1.0 - miscibility;
            kro += miscibility * mkro;
        }
 
        // compute the mobility of the solvent "phase" and modify the gas phase
        const auto& ssfnKrg = SolventModule::ssfnKrg(elemCtx, dofIdx, timeIdx);
        const auto& ssfnKrs = SolventModule::ssfnKrs(elemCtx, dofIdx, timeIdx);
 
        Evaluation& krg = asImp_().mobility_[gasPhaseIdx];
        solventMobility_ = krg * ssfnKrs.eval(Fsolgas, /*extrapolate=*/true);
        krg *= ssfnKrg.eval(Fhydgas, /*extrapolate=*/true);
    }
 
    void solventPvtUpdate_(const ElementContext& elemCtx,
                           unsigned scvIdx,
                           unsigned timeIdx)
    {
        const auto& iq = asImp_();
        const unsigned pvtRegionIdx = iq.pvtRegionIndex();
        const Evaluation& T = iq.fluidState().temperature(gasPhaseIdx);
        const Evaluation& p = iq.fluidState().pressure(gasPhaseIdx);
 
        const Evaluation rv = 0.0;
        const Evaluation rvw = 0.0;
        if (SolventModule::isCO2Sol() || SolventModule::isH2Sol() ){
            if (SolventModule::isCO2Sol()) {
                const auto& co2gasPvt = SolventModule::co2GasPvt();
                solventInvFormationVolumeFactor_ =
                    co2gasPvt.inverseFormationVolumeFactor(pvtRegionIdx, T, p, rv, rvw);
                solventRefDensity_ = co2gasPvt.gasReferenceDensity(pvtRegionIdx);
                solventViscosity_ = co2gasPvt.viscosity(pvtRegionIdx, T, p, rv, rvw);
 
                const auto& brineCo2Pvt = SolventModule::brineCo2Pvt();
                auto& fs = asImp_().fluidState_;
                const auto& bw = brineCo2Pvt.inverseFormationVolumeFactor(pvtRegionIdx, T, p, rsSolw());
 
                const auto denw = bw * brineCo2Pvt.waterReferenceDensity(pvtRegionIdx) +
                                  rsSolw() * bw * brineCo2Pvt.gasReferenceDensity(pvtRegionIdx);
                fs.setDensity(waterPhaseIdx, denw);
                fs.setInvB(waterPhaseIdx, bw);
                Evaluation& mobw = asImp_().mobility_[waterPhaseIdx];
                const auto& muWat = fs.viscosity(waterPhaseIdx);
                const auto& muWatEff = brineCo2Pvt.viscosity(pvtRegionIdx, T, p, rsSolw());
                mobw *= muWat / muWatEff;
            } else { 
                const auto& h2gasPvt = SolventModule::h2GasPvt();
                solventInvFormationVolumeFactor_ =
                    h2gasPvt.inverseFormationVolumeFactor(pvtRegionIdx, T, p, rv, rvw);
                solventRefDensity_ = h2gasPvt.gasReferenceDensity(pvtRegionIdx);
                solventViscosity_ = h2gasPvt.viscosity(pvtRegionIdx, T, p, rv, rvw); 
            
                const auto& brineH2Pvt = SolventModule::brineH2Pvt();
                auto& fs = asImp_().fluidState_;
                const auto& bw = brineH2Pvt.inverseFormationVolumeFactor(pvtRegionIdx, T, p, rsSolw());
 
                const auto denw = bw * brineH2Pvt.waterReferenceDensity(pvtRegionIdx) +
                                  rsSolw() * bw * brineH2Pvt.gasReferenceDensity(pvtRegionIdx);
                fs.setDensity(waterPhaseIdx, denw);
                fs.setInvB(waterPhaseIdx, bw);
                Evaluation& mobw = asImp_().mobility_[waterPhaseIdx];
                const auto& muWat = fs.viscosity(waterPhaseIdx);
                const auto& muWatEff = brineH2Pvt.viscosity(pvtRegionIdx, T, p, rsSolw());
                mobw *= muWat / muWatEff;
            }
        } else {
            const auto& solventPvt = SolventModule::solventPvt();
            solventInvFormationVolumeFactor_ = solventPvt.inverseFormationVolumeFactor(pvtRegionIdx, T, p);
            solventRefDensity_ = solventPvt.referenceDensity(pvtRegionIdx);
            solventViscosity_ = solventPvt.viscosity(pvtRegionIdx, T, p);
        }   
 
        solventDensity_ = solventInvFormationVolumeFactor_*solventRefDensity_;
        effectiveProperties(elemCtx, scvIdx, timeIdx);
 
        solventMobility_ /= solventViscosity_;
    }
 
    const Evaluation& solventSaturation() const
    { return solventSaturation_; }
 
    const Evaluation& rsSolw() const
    { return rsSolw_; }
 
    const Evaluation& solventDensity() const
    { return solventDensity_; }
 
    const Evaluation& solventViscosity() const
    { return solventViscosity_; }
 
    const Evaluation& solventMobility() const
    { return solventMobility_; }
 
    const Evaluation& solventInverseFormationVolumeFactor() const
    { return solventInvFormationVolumeFactor_; }
 
    // This could be stored pr pvtRegion instead
    Scalar solventRefDensity() const
    { return solventRefDensity_; }
 
private:
    // Computes the effective properties based on
    // Todd-Longstaff mixing model.
    void effectiveProperties(const ElementContext& elemCtx,
                             unsigned scvIdx,
                             unsigned timeIdx)
    {
        if (!SolventModule::isMiscible()) {
            return;
        }
 
        // Don't waste calculations if no solvent
        // Apply a cut-off for small and negative solvent saturations
        if (solventSaturation() < cutOff) {
            return;
        }
 
        // We plan to update the fluidstate with the effective
        // properties
        auto& fs = asImp_().fluidState_;
 
        // Compute effective saturations
        Evaluation oilEffSat = 0.0;
        if (FluidSystem::phaseIsActive(oilPhaseIdx)) {
            oilEffSat = fs.saturation(oilPhaseIdx);
        }
        Evaluation gasEffSat = fs.saturation(gasPhaseIdx);
        Evaluation solventEffSat = solventSaturation();
        if (FluidSystem::phaseIsActive(waterPhaseIdx)) {
            const auto& sorwmis = SolventModule::sorwmis(elemCtx, scvIdx, timeIdx);
            const auto& sgcwmis = SolventModule::sgcwmis(elemCtx, scvIdx, timeIdx);
            const Evaluation zero = 0.0;
            const Evaluation& sw = fs.saturation(waterPhaseIdx);
            if (FluidSystem::phaseIsActive(oilPhaseIdx)) {
                oilEffSat = std::max(oilEffSat - sorwmis.eval(sw,  /*extrapolate=*/true), zero);
            }
            gasEffSat = std::max(gasEffSat - sgcwmis.eval(sw,  /*extrapolate=*/true), zero);
            solventEffSat = std::max(solventEffSat - sgcwmis.eval(sw,  /*extrapolate=*/true), zero);
        }
        const Evaluation oilGasSolventEffSat =  oilEffSat + gasEffSat + solventEffSat;
        const Evaluation oilSolventEffSat = oilEffSat + solventEffSat;
        const Evaluation solventGasEffSat = solventEffSat + gasEffSat;
 
        // Compute effective viscosities
 
        // Mixing parameter for viscosity
        // The pressureMixingParameter represent the miscibility of the solvent while the mixingParameterViscosity the effect of the porous media.
        // The pressureMixingParameter is not implemented in ecl100.
        const Evaluation& p =
            FluidSystem::phaseIsActive(oilPhaseIdx)
                ? fs.pressure(oilPhaseIdx)
                : fs.pressure(gasPhaseIdx);
        // account for pressure effects
        const auto& pmiscTable = SolventModule::pmisc(elemCtx, scvIdx, timeIdx);
        const Evaluation pmisc = pmiscTable.eval(p, /*extrapolate=*/true);
        const auto& tlPMixTable = SolventModule::tlPMixTable(elemCtx, scvIdx, timeIdx);
        const Evaluation tlMixParamMu = SolventModule::tlMixParamViscosity(elemCtx, scvIdx, timeIdx) *
                                        tlPMixTable.eval(p,  /*extrapolate=*/true);
 
        const Evaluation& muGas = fs.viscosity(gasPhaseIdx);
        const Evaluation& muSolvent = solventViscosity_;
 
        assert(muGas.value() > 0);
        assert(muSolvent.value() > 0);
        const Evaluation muGasPow = pow(muGas, 0.25);
        const Evaluation muSolventPow = pow(muSolvent, 0.25);
 
        Evaluation muMixSolventGas = muGas;
        if (solventGasEffSat > cutOff) {
            muMixSolventGas *= muSolvent / pow(((gasEffSat / solventGasEffSat) * muSolventPow) +
                                               ((solventEffSat / solventGasEffSat) * muGasPow), 4.0);
        }
 
        Evaluation muOil = 1.0;
        Evaluation muOilPow = 1.0;
        Evaluation muMixOilSolvent = 1.0;
        Evaluation muOilEff = 1.0;
        if (FluidSystem::phaseIsActive(oilPhaseIdx)) {
            muOil = fs.viscosity(oilPhaseIdx);
            assert(muOil.value() > 0);
            muOilPow = pow(muOil, 0.25);
            muMixOilSolvent = muOil;
            if (oilSolventEffSat > cutOff) {
                muMixOilSolvent *= muSolvent / pow(((oilEffSat / oilSolventEffSat) * muSolventPow) +
                                                   ((solventEffSat / oilSolventEffSat) * muOilPow), 4.0);
            }
 
            muOilEff = pow(muOil,1.0 - tlMixParamMu) * pow(muMixOilSolvent, tlMixParamMu);
        }
        Evaluation muMixSolventGasOil = muOil;
        if (oilGasSolventEffSat > cutOff) {
            muMixSolventGasOil *= muSolvent * muGas / pow(((oilEffSat / oilGasSolventEffSat) *
                                                           muSolventPow * muGasPow) +
                                                          ((solventEffSat / oilGasSolventEffSat) *
                                                           muOilPow *  muGasPow) +
                                                            ((gasEffSat / oilGasSolventEffSat) *
                                                             muSolventPow * muOilPow), 4.0);
        }
 
        Evaluation muGasEff = pow(muGas,1.0 - tlMixParamMu) * pow(muMixSolventGas, tlMixParamMu);
        const Evaluation muSolventEff = pow(muSolvent,1.0 - tlMixParamMu) * pow(muMixSolventGasOil, tlMixParamMu);
 
        // Compute effective densities
        const Evaluation& rhoGas = fs.density(gasPhaseIdx);
        Evaluation rhoOil = 0.0;
        if (FluidSystem::phaseIsActive(oilPhaseIdx)) {
            rhoOil = fs.density(oilPhaseIdx);
        }
 
        const Evaluation& rhoSolvent = solventDensity_;
 
        // Mixing parameter for density
        // The pressureMixingParameter represent the miscibility of the
        // solvent while the mixingParameterDenisty the effect of the porous media.
        // The pressureMixingParameter is not implemented in ecl100.
        const Evaluation tlMixParamRho = SolventModule::tlMixParamDensity(elemCtx, scvIdx, timeIdx) *
                                         tlPMixTable.eval(p,  /*extrapolate=*/true);
 
        // compute effective viscosities for density calculations. These have to
        // be recomputed as a different mixing parameter may be used.
        const Evaluation muOilEffPow = pow(pow(muOil, 1.0 - tlMixParamRho) *
                                           pow(muMixOilSolvent, tlMixParamRho), 0.25);
        const Evaluation muGasEffPow = pow(pow(muGas, 1.0 - tlMixParamRho) *
                                           pow(muMixSolventGas, tlMixParamRho), 0.25);
        const Evaluation muSolventEffPow = pow(pow(muSolvent, 1.0 - tlMixParamRho) *
                                               pow(muMixSolventGasOil, tlMixParamRho), 0.25);
 
        const Evaluation oilGasEffSaturation = oilEffSat + gasEffSat;
        Evaluation sof = 0.0;
        Evaluation sgf = 0.0;
        if (oilGasEffSaturation.value() > cutOff) {
            sof = oilEffSat / oilGasEffSaturation;
            sgf = gasEffSat / oilGasEffSaturation;
        }
 
        const Evaluation muSolventOilGasPow = muSolventPow * ((sgf * muOilPow) + (sof * muGasPow));
 
        Evaluation rhoMixSolventGasOil = 0.0;
        if (oilGasSolventEffSat.value() > cutOff) {
            rhoMixSolventGasOil = (rhoOil * oilEffSat / oilGasSolventEffSat) +
                                  (rhoGas * gasEffSat / oilGasSolventEffSat) +
                                  (rhoSolvent * solventEffSat / oilGasSolventEffSat);
        }
 
        Evaluation rhoGasEff = 0.0;
        if (std::abs(muSolventPow.value() - muGasPow.value()) < cutOff) {
            rhoGasEff = ((1.0 - tlMixParamRho) * rhoGas) +
                        (tlMixParamRho * rhoMixSolventGasOil);
        }
        else {
            const Evaluation solventGasEffFraction = (muGasPow * (muSolventPow - muGasEffPow)) /
                                                     (muGasEffPow * (muSolventPow - muGasPow));
            rhoGasEff = (rhoGas * solventGasEffFraction) + (rhoSolvent * (1.0 - solventGasEffFraction));
        }
 
        Evaluation rhoSolventEff = 0.0;
        if (std::abs((muSolventOilGasPow.value() - (muOilPow.value() * muGasPow.value()))) < cutOff) {
            rhoSolventEff = ((1.0 - tlMixParamRho) * rhoSolvent) + (tlMixParamRho * rhoMixSolventGasOil);
        }
        else {
            const Evaluation sfraction_se = (muSolventOilGasPow -
                                             muOilPow * muGasPow * muSolventPow / muSolventEffPow) /
                                            (muSolventOilGasPow - (muOilPow * muGasPow));
            rhoSolventEff = (rhoSolvent * sfraction_se) +
                            (rhoGas * sgf * (1.0 - sfraction_se)) +
                            (rhoOil * sof * (1.0 - sfraction_se));
        }
 
        // compute invB from densities.
        const unsigned pvtRegionIdx = asImp_().pvtRegionIndex();
        Evaluation bGasEff = rhoGasEff;
        if (FluidSystem::phaseIsActive(oilPhaseIdx)) {
            bGasEff /= (FluidSystem::referenceDensity(gasPhaseIdx, pvtRegionIdx) +
                        FluidSystem::referenceDensity(oilPhaseIdx, pvtRegionIdx) * fs.Rv());
        } else {
            bGasEff /= (FluidSystem::referenceDensity(gasPhaseIdx, pvtRegionIdx));
        }
        const Evaluation bSolventEff = rhoSolventEff / solventRefDensity();
 
        // copy the unmodified invB factors
        const Evaluation bg = fs.invB(gasPhaseIdx);
        const Evaluation bs = solventInverseFormationVolumeFactor();
        const Evaluation bg_eff = pmisc * bGasEff + (1.0 - pmisc) * bg;
        const Evaluation bs_eff = pmisc * bSolventEff + (1.0 - pmisc) * bs;
 
        // set the densities
        if (FluidSystem::phaseIsActive(oilPhaseIdx)) {
            fs.setDensity(gasPhaseIdx,
                          bg_eff *
                         (FluidSystem::referenceDensity(gasPhaseIdx, pvtRegionIdx) +
                          FluidSystem::referenceDensity(oilPhaseIdx, pvtRegionIdx)*fs.Rv()));
        } else {
            fs.setDensity(gasPhaseIdx,
                          bg_eff * FluidSystem::referenceDensity(gasPhaseIdx, pvtRegionIdx));
        }
        solventDensity_ = bs_eff * solventRefDensity();
 
        // set the mobility
        Evaluation& mobg = asImp_().mobility_[gasPhaseIdx];
        muGasEff = bg_eff / (pmisc * bGasEff / muGasEff + (1.0 - pmisc) * bg / muGas);
        mobg *= muGas / muGasEff;
 
        // Update viscosity of solvent
        solventViscosity_ = bs_eff / (pmisc * bSolventEff / muSolventEff +
                            (1.0 - pmisc) * bs / muSolvent);
 
        if (FluidSystem::phaseIsActive(oilPhaseIdx)) {
            Evaluation rhoOilEff = 0.0;
            if (std::abs(muOilPow.value() - muSolventPow.value()) < cutOff) {
                rhoOilEff = ((1.0 - tlMixParamRho) * rhoOil) + (tlMixParamRho * rhoMixSolventGasOil);
            }
            else {
                const Evaluation solventOilEffFraction = (muOilPow * (muOilEffPow - muSolventPow)) /
                                                         (muOilEffPow * (muOilPow - muSolventPow));
                rhoOilEff = (rhoOil * solventOilEffFraction) + (rhoSolvent * (1.0 - solventOilEffFraction));
            }
            const Evaluation bOilEff =
                rhoOilEff / (FluidSystem::referenceDensity(oilPhaseIdx, pvtRegionIdx) +
                             FluidSystem::referenceDensity(gasPhaseIdx, pvtRegionIdx) * fs.Rs());
            const Evaluation bo = fs.invB(oilPhaseIdx);
            const Evaluation bo_eff = pmisc * bOilEff + (1.0 - pmisc) * bo;
            fs.setDensity(oilPhaseIdx,
                bo_eff * (FluidSystem::referenceDensity(oilPhaseIdx, pvtRegionIdx) +
                          FluidSystem::referenceDensity(gasPhaseIdx, pvtRegionIdx) * fs.Rs()));
 
            // keep the mu*b interpolation
            Evaluation& mobo = asImp_().mobility_[oilPhaseIdx];
            muOilEff = bo_eff / (pmisc * bOilEff / muOilEff + (1.0 - pmisc) * bo / muOil);
            mobo *= muOil / muOilEff;
        }
    }
 
protected:
    Implementation& asImp_()
    { return *static_cast<Implementation*>(this); }
 
    Evaluation hydrocarbonSaturation_;
    Evaluation solventSaturation_;
    Evaluation rsSolw_;
    Evaluation solventDensity_;
    Evaluation solventViscosity_;
    Evaluation solventMobility_;
    Evaluation solventInvFormationVolumeFactor_;
 
    Scalar solventRefDensity_;
};
 
template <class TypeTag>
class BlackOilSolventIntensiveQuantities<TypeTag, false>
{
    using Evaluation = GetPropType<TypeTag, Properties::Evaluation>;
    using ElementContext = GetPropType<TypeTag, Properties::ElementContext>;
    using Scalar = GetPropType<TypeTag, Properties::Scalar>;
 
public:
    void solventPreSatFuncUpdate_(const ElementContext&,
                                  unsigned,
                                  unsigned)
    {}
 
    void solventPostSatFuncUpdate_(const ElementContext&,
                                   unsigned,
                                   unsigned)
    {}
 
    void solventPvtUpdate_(const ElementContext&,
                           unsigned,
                           unsigned)
    {}
 
    const Evaluation& solventSaturation() const
    { throw std::runtime_error("solventSaturation() called but solvents are disabled"); }
 
    const Evaluation& rsSolw() const
    { throw std::runtime_error("rsSolw() called but solvents are disabled"); }
 
    const Evaluation& solventDensity() const
    { throw std::runtime_error("solventDensity() called but solvents are disabled"); }
 
    const Evaluation& solventViscosity() const
    { throw std::runtime_error("solventViscosity() called but solvents are disabled"); }
 
    const Evaluation& solventMobility() const
    { throw std::runtime_error("solventMobility() called but solvents are disabled"); }
 
    const Evaluation& solventInverseFormationVolumeFactor() const
    { throw std::runtime_error("solventInverseFormationVolumeFactor() called but solvents are disabled"); }
 
    Scalar solventRefDensity() const
    { throw std::runtime_error("solventRefDensity() called but solvents are disabled"); }
};
 
template <class TypeTag, bool enableSolventV = getPropValue<TypeTag, Properties::EnableSolvent>()>
class BlackOilSolventExtensiveQuantities
{
    using Implementation = GetPropType<TypeTag, Properties::ExtensiveQuantities>;
 
    using Scalar = GetPropType<TypeTag, Properties::Scalar>;
    using Evaluation = GetPropType<TypeTag, Properties::Evaluation>;
    using ElementContext = GetPropType<TypeTag, Properties::ElementContext>;
    using IntensiveQuantities = GetPropType<TypeTag, Properties::IntensiveQuantities>;
    using ExtensiveQuantities = GetPropType<TypeTag, Properties::ExtensiveQuantities>;
    using FluidSystem = GetPropType<TypeTag, Properties::FluidSystem>;
    using GridView = GetPropType<TypeTag, Properties::GridView>;
 
    using Toolbox = MathToolbox<Evaluation>;
 
    static constexpr unsigned gasPhaseIdx = FluidSystem::gasPhaseIdx;
    static constexpr int dimWorld = GridView::dimensionworld;
 
    using DimVector = Dune::FieldVector<Scalar, dimWorld>;
    using DimEvalVector = Dune::FieldVector<Evaluation, dimWorld>;
 
public:
    template <class Dummy = bool> // we need to make this method a template to avoid
                                  // compiler errors if it is not instantiated!
    void updateVolumeFluxPerm(const ElementContext& elemCtx,
                              unsigned scvfIdx,
                              unsigned timeIdx)
    {
        const auto& gradCalc = elemCtx.gradientCalculator();
        PressureCallback<TypeTag> pressureCallback(elemCtx);
 
        const auto& scvf = elemCtx.stencil(timeIdx).interiorFace(scvfIdx);
        const auto& faceNormal = scvf.normal();
 
        const unsigned i = scvf.interiorIndex();
        const unsigned j = scvf.exteriorIndex();
 
        // calculate the "raw" pressure gradient
        DimEvalVector solventPGrad;
        pressureCallback.setPhaseIndex(gasPhaseIdx);
        gradCalc.calculateGradient(solventPGrad,
                                   elemCtx,
                                   scvfIdx,
                                   pressureCallback);
        Valgrind::CheckDefined(solventPGrad);
 
        // correct the pressure gradients by the gravitational acceleration
        if (Parameters::Get<Parameters::EnableGravity>()) {
            // estimate the gravitational acceleration at a given SCV face
            // using the arithmetic mean
            const auto& gIn = elemCtx.problem().gravity(elemCtx, i, timeIdx);
            const auto& gEx = elemCtx.problem().gravity(elemCtx, j, timeIdx);
 
            const auto& intQuantsIn = elemCtx.intensiveQuantities(i, timeIdx);
            const auto& intQuantsEx = elemCtx.intensiveQuantities(j, timeIdx);
 
            const auto& posIn = elemCtx.pos(i, timeIdx);
            const auto& posEx = elemCtx.pos(j, timeIdx);
            const auto& posFace = scvf.integrationPos();
 
            // the distance between the centers of the control volumes
            DimVector distVecIn(posIn);
            DimVector distVecEx(posEx);
            DimVector distVecTotal(posEx);
 
            distVecIn -= posFace;
            distVecEx -= posFace;
            distVecTotal -= posIn;
            const Scalar absDistTotalSquared = distVecTotal.two_norm2();
 
            // calculate the hydrostatic pressure at the integration point of the face
            auto rhoIn = intQuantsIn.solventDensity();
            auto pStatIn = - rhoIn * (gIn * distVecIn);
 
            // the quantities on the exterior side of the face do not influence the
            // result for the TPFA scheme, so they can be treated as scalar values.
            Scalar rhoEx = Toolbox::value(intQuantsEx.solventDensity());
            Scalar pStatEx = - rhoEx * (gEx * distVecEx);
 
            // compute the hydrostatic gradient between the two control volumes (this
            // gradient exhibitis the same direction as the vector between the two
            // control volume centers and the length (pStaticExterior -
            // pStaticInterior)/distanceInteriorToExterior
            DimEvalVector f(distVecTotal);
            f *= (pStatEx - pStatIn) / absDistTotalSquared;
 
            // calculate the final potential gradient
            for (unsigned dimIdx = 0; dimIdx < dimWorld; ++dimIdx) {
                solventPGrad[dimIdx] += f[dimIdx];
 
                if (!isfinite(solventPGrad[dimIdx])) {
                    throw NumericalProblem("Non-finite potential gradient for solvent 'phase'");
                }
            }
        }
 
        // determine the upstream and downstream DOFs
        Evaluation solventPGradNormal = 0.0;
        for (unsigned dimIdx = 0; dimIdx < faceNormal.size(); ++dimIdx) {
            solventPGradNormal += solventPGrad[dimIdx]*faceNormal[dimIdx];
        }
 
        if (solventPGradNormal > 0) {
            solventUpstreamDofIdx_ = j;
            solventDownstreamDofIdx_ = i;
        }
        else {
            solventUpstreamDofIdx_ = i;
            solventDownstreamDofIdx_ = j;
        }
 
        const auto& up = elemCtx.intensiveQuantities(solventUpstreamDofIdx_, timeIdx);
 
        // this is also slightly hacky because it assumes that the derivative of the
        // flux between two DOFs only depends on the primary variables in the
        // upstream direction. For non-TPFA flux approximation schemes, this is not
        // true...
        if (solventUpstreamDofIdx_ == i) {
            solventVolumeFlux_ = solventPGradNormal * up.solventMobility();
        }
        else {
            solventVolumeFlux_ = solventPGradNormal * scalarValue(up.solventMobility());
        }
    }
 
    template <class Dummy = bool> // we need to make this method a template to avoid
                                  // compiler errors if it is not instantiated!
    void updateVolumeFluxTrans(const ElementContext& elemCtx,
                               unsigned scvfIdx,
                               unsigned timeIdx)
    {
        const ExtensiveQuantities& extQuants = asImp_();
 
        const unsigned interiorDofIdx = extQuants.interiorIndex();
        const unsigned exteriorDofIdx = extQuants.exteriorIndex();
        assert(interiorDofIdx != exteriorDofIdx);
 
        const auto& intQuantsIn = elemCtx.intensiveQuantities(interiorDofIdx, timeIdx);
        const auto& intQuantsEx = elemCtx.intensiveQuantities(exteriorDofIdx, timeIdx);
 
        const unsigned I = elemCtx.globalSpaceIndex(interiorDofIdx, timeIdx);
        const unsigned J = elemCtx.globalSpaceIndex(exteriorDofIdx, timeIdx);
 
        const Scalar thpres = elemCtx.problem().thresholdPressure(I, J);
        const Scalar trans = elemCtx.problem().transmissibility(elemCtx, interiorDofIdx, exteriorDofIdx);
        const Scalar g = elemCtx.problem().gravity()[dimWorld - 1];
 
        const Scalar zIn = elemCtx.problem().dofCenterDepth(elemCtx, interiorDofIdx, timeIdx);
        const Scalar zEx = elemCtx.problem().dofCenterDepth(elemCtx, exteriorDofIdx, timeIdx);
        const Scalar distZ = zIn - zEx;
 
        const Evaluation& rhoIn = intQuantsIn.solventDensity();
        const Scalar rhoEx = Toolbox::value(intQuantsEx.solventDensity());
        const Evaluation& rhoAvg = rhoIn * 0.5 + rhoEx * 0.5;
 
        const Evaluation& pressureInterior = intQuantsIn.fluidState().pressure(gasPhaseIdx);
        Evaluation pressureExterior = Toolbox::value(intQuantsEx.fluidState().pressure(gasPhaseIdx));
        pressureExterior += distZ * g * rhoAvg;
 
        Evaluation pressureDiffSolvent = pressureExterior - pressureInterior;
        if (std::abs(scalarValue(pressureDiffSolvent)) > thpres) {
            if (pressureDiffSolvent < 0.0) {
                pressureDiffSolvent += thpres;
            }
            else {
                pressureDiffSolvent -= thpres;
            }
        }
        else {
            pressureDiffSolvent = 0.0;
        }
 
        if (pressureDiffSolvent > 0.0) {
            solventUpstreamDofIdx_ = exteriorDofIdx;
            solventDownstreamDofIdx_ = interiorDofIdx;
        }
        else if (pressureDiffSolvent < 0.0) {
            solventUpstreamDofIdx_ = interiorDofIdx;
            solventDownstreamDofIdx_ = exteriorDofIdx;
        }
        else {
            // pressure potential gradient is zero; force consistent upstream and
            // downstream indices over the intersection regardless of the side which it
            // is looked at.
            solventUpstreamDofIdx_ = std::min(interiorDofIdx, exteriorDofIdx);
            solventDownstreamDofIdx_ = std::max(interiorDofIdx, exteriorDofIdx);
            solventVolumeFlux_ = 0.0;
            return;
        }
 
        const Scalar faceArea = elemCtx.stencil(timeIdx).interiorFace(scvfIdx).area();
        const IntensiveQuantities& up = elemCtx.intensiveQuantities(solventUpstreamDofIdx_, timeIdx);
        if (solventUpstreamDofIdx_ == interiorDofIdx) {
            solventVolumeFlux_ = up.solventMobility() * (-trans / faceArea) * pressureDiffSolvent;
        }
        else {
            solventVolumeFlux_ =
                scalarValue(up.solventMobility()) * (-trans / faceArea) * pressureDiffSolvent;
        }
    }
 
    unsigned solventUpstreamIndex() const
    { return solventUpstreamDofIdx_; }
 
    unsigned solventDownstreamIndex() const
    { return solventDownstreamDofIdx_; }
 
    const Evaluation& solventVolumeFlux() const
    { return solventVolumeFlux_; }
 
    void setSolventVolumeFlux(const Evaluation& solventVolumeFlux)
    { solventVolumeFlux_ = solventVolumeFlux; }
 
private:
    Implementation& asImp_()
    { return *static_cast<Implementation*>(this); }
 
    Evaluation solventVolumeFlux_;
    unsigned solventUpstreamDofIdx_;
    unsigned solventDownstreamDofIdx_;
};
 
template <class TypeTag>
class BlackOilSolventExtensiveQuantities<TypeTag, false>
{
    using ElementContext = GetPropType<TypeTag, Properties::ElementContext>;
    using Evaluation = GetPropType<TypeTag, Properties::Evaluation>;
 
public:
    void updateVolumeFluxPerm(const ElementContext&,
                              unsigned,
                              unsigned)
    {}
 
    void updateVolumeFluxTrans(const ElementContext&,
                               unsigned,
                               unsigned)
    {}
 
    unsigned solventUpstreamIndex() const
    { throw std::runtime_error("solventUpstreamIndex() called but solvents are disabled"); }
 
    unsigned solventDownstreamIndex() const
    { throw std::runtime_error("solventDownstreamIndex() called but solvents are disabled"); }
 
    const Evaluation& solventVolumeFlux() const
    { throw std::runtime_error("solventVolumeFlux() called but solvents are disabled"); }
 
    void setSolventVolumeFlux(const Evaluation& /* solventVolumeFlux */)
    { throw std::runtime_error("setSolventVolumeFlux() called but solvents are disabled"); }
};
 
} // namespace Opm
 
#endif